* Investigation into Zhou Yongkang has broadened in past four months
* Relatives and associates have had bank accounts frozen - sources
* Bonds, apartments, cars, paintings, cash and gold seized - sources
* Most seized assets not in Zhou's name - sources
* More than 300 relatives, allies, staff detained or questioned - sources
By Benjamin Kang Lim and Ben Blanchard
BEIJING, March 30 (Reuters) - Chinese authorities have seized assets worth at least 90 billion yuan ($14.5 billion) from family members and associates of retired domestic security tsar Zhou Yongkang, who is at the centre of China's biggest corruption scandal in more than six decades, two sources said.
More than 300 of Zhou's relatives, political allies, proteges and staff have also been taken into custody or questioned in the past four months, the sources, who have been briefed on the investigation, told Reuters.
The sheer size of the asset seizures and the scale of the investigations into the people around Zhou - both unreported until now - make the corruption probe unprecedented in modern China and would appear to show that President Xi Jinping is tackling graft at the highest levels.
But it may also be driven partly by political payback after Zhou angered leaders such as Xi by opposing the ouster of former high-flying politician Bo Xilai, who was jailed for life in September for corruption and abuse of power.
Zhou, 71, has been under virtual house arrest since authorities began formally investigating him late last year. He is the most senior Chinese politician to be ensnared in a corruption investigation since the Communist Party swept to power in 1949.
"It's the ugliest in the history of the New China," said one of the sources, who has ties to the leadership, requesting anonymity to avoid repercussions for speaking to the foreign media about elite politics.
The government has yet to make any official statement about Zhou or the case against him and it has not been possible to contact Zhou, his family, associates or staff for comment. It is not clear if any of them have lawyers.
The party's anti-corruption watchdog and the prosecutor's office did not respond to requests for comment. In the secretive world of China's Communist Party, targets of its investigations usually disappear, often for months or even years, until an official announcement is made.
Xi ordered a task force formed in late November or early December to look into accusations against Zhou, sources have previously told Reuters. They have not said what the allegations were except that they were related to violating party discipline, official jargon for corruption.
A third source with ties to the leadership said Zhou had refused to cooperate with investigators, insisting he was the victim of a power struggle.
"Zhou Yongkang is tough and claims it's political persecution," the source said.
Zhou rose through the ranks of China's oil and gas sector before joining the elite Politburo Standing Committee in 2007, where as domestic security chief his budget exceeded defence spending. He retired in 2012 and was last seen at an alumni event at the China University of Petroleum on Oct. 1.
BONDS, VILLAS, CARS, LIQUOR, GOLD
The first two sources said prosecutors and the party's anti-corruption watchdog had frozen bank accounts with deposits totaling 37 billion yuan and seized domestic and overseas bonds and stocks with a combined value of 51 billion yuan after raiding homes in Beijing, Shanghai and five provinces.
Investigators had also confiscated about 300 apartments and villas worth around 1.7 billion yuan, antiques and contemporary paintings with a market value of 1 billion yuan and more than 60 vehicles, the sources added. Other items seized included expensive liquor, gold, silver and cash in local and foreign currencies.
The seized assets belonged to those in custody, the sources said, without saying how many people in total had been detained compared to just questioned. Most of the assets were not in Zhou's name, they added.
According to the sources, the seized assets had a combined value of at least 90 billion yuan, although it was unclear what share of that total was ill-gotten and would be turned over to the state.
The amount eventually made public could be smaller to avoid embarrassing the party and angering ordinary Chinese, the sources said.
Such asset seizures, while large, are not uncommon in China, where excess has often been revealed from graft probes in recent years. In January, the respected Chinese magazine Caixin said authorities had seized a solid gold statue of Mao Zedong among other things from the mansion of a senior military officer who has been under investigation since he was sacked in 2012.
The first two sources added that more than 10 of Zhou's relatives had been detained. They included Zhou's one-time television reporter wife Jia Xiaoye, his eldest son from a previous marriage Zhou Bin, Zhou Bin's in-laws and Zhou Yongkang's brother.
About 10 officials who held a rank equivalent to at least vice minister were also under investigation, the sources said.
Among them were Jiang Jiemin, former chairman of both state energy giant PetroChina and its parent China National Petroleum Corporation (CNPC), former Vice Minister of Public Security Li Dongsheng and Ji Wenlin, ex-vice governor of the southernmost island province of Hainan.
Chinese state media has announced that all three were being investigated for serious violations of discipline. They were either proteges or aides to Zhou.
Reuters has been unable to contact the three men. It's unclear if they have lawyers.
More than 20 of Zhou's bodyguards, secretaries and drivers had also been detained, the sources said. Many other family members and associates had been questioned.
THE BIGGEST TIGER?
Since becoming head of the party in late 2012 and then president a year ago, Xi has vowed to go after both powerful "tigers" and lowly "flies" in an effort to crack down on the corruption he says threatens the party's very existence.
But Xi is in a dilemma over whether to put Zhou on trial lest it further undermine public faith in the party, the three sources said, referring to the growing disillusionment in China over rampant graft and abuse of power.
Xi would also risk alienating other party elders who fear that they and their families could be next, political analysts say.
Putting someone as powerful as Zhou in the dock would be a political decision that only Xi could make after getting the consensus of senior party members, Xi's predecessors and other retired top officials, they say.
In ordering the investigation, Xi broke with an unwritten rule that incumbent and retired members of the Standing Committee were immune from prosecution.
As a member of the Standing Committee, the apex of power in China, and a former domestic security chief, Zhou would have intimate knowledge of the skeletons in the party's closet.
It is still unclear exactly why Zhou has been targeted, though an early sign that he might have overstepped was when he retired and the position of domestic security chief was dropped from the Standing Committee.
Sources have also said Zhou angered Xi and other leaders over Bo Xilai, whose career was ended in 2012 by a murder scandal in which his wife was eventually convicted of poisoning a British businessman who had been a family friend.
Before Bo's downfall, Zhou had recommended that Bo succeed him as domestic security chief, multiple sources with direct knowledge of the matter have said. ($1 = 6.2122 Chinese yuan) (Editing by Dean Yates)